Bombs made of cast iron shells packed with explosive gunpowder date to 13th century China. In 1232, as the Mongol general Subutai (1176–1248) descended on the Jin stronghold of Kaifeng, the defenders had a "thunder crash bomb" which "consisted of gunpowder put into an iron container ... then when the fuse was lit (and the projectile shot off) there was a great explosion the noise whereof was like thunder, audible for more than thirty miles.

- Wikipedia.org